Glass formation via structural fragmentation of a 2D coordination network.

نویسندگان

  • D Umeyama
  • N P Funnell
  • M J Cliffe
  • J A Hill
  • A L Goodwin
  • Y Hijikata
  • T Itakura
  • T Okubo
  • S Horike
  • S Kitagawa
چکیده

The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.

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عنوان ژورنال:
  • Chemical communications

دوره 51 64  شماره 

صفحات  -

تاریخ انتشار 2015